一、氮氣孔的(de)形成機理(li)


  在21.5Cr5Mn1.5Ni0.25N含(han)氮(dan)(dan)雙相(xiang)(xiang)鋼凝(ning)(ning)固(gu)過(guo)程(cheng)中,氮(dan)(dan)氣(qi)孔形成(cheng)和(he)(he)凝(ning)(ning)固(gu)前沿(yan)處[%N]1iq隨(sui)距離(li)變化(hua)的(de)(de)(de)(de)(de)(de)(de)規律如圖2-55所(suo)示(shi)。由(you)于糊狀(zhuang)區(qu)(qu)內大(da)量(liang)枝(zhi)(zhi)(zhi)晶網狀(zhuang)結構的(de)(de)(de)(de)(de)(de)(de)形成(cheng),液(ye)(ye)相(xiang)(xiang)的(de)(de)(de)(de)(de)(de)(de)對流(liu)只(zhi)存在于一次枝(zhi)(zhi)(zhi)晶尖端位置附近。且枝(zhi)(zhi)(zhi)晶間(jian)(jian)(jian)幾(ji)乎無(wu)液(ye)(ye)相(xiang)(xiang)的(de)(de)(de)(de)(de)(de)(de)流(liu)動(dong)。因此,枝(zhi)(zhi)(zhi)晶間(jian)(jian)(jian)殘余液(ye)(ye)相(xiang)(xiang)中的(de)(de)(de)(de)(de)(de)(de)氮(dan)(dan)傳(chuan)質(zhi)主要依靠氮(dan)(dan)的(de)(de)(de)(de)(de)(de)(de)擴(kuo)散行為,且糊狀(zhuang)區(qu)(qu)內氮(dan)(dan)傳(chuan)質(zhi)速(su)率非常小(xiao)。初始相(xiang)(xiang)貧氮(dan)(dan)鐵(tie)素體(ti)(ti)相(xiang)(xiang)8的(de)(de)(de)(de)(de)(de)(de)氮(dan)(dan)溶解(jie)度(du)和(he)(he)糊狀(zhuang)區(qu)(qu)的(de)(de)(de)(de)(de)(de)(de)氮(dan)(dan)傳(chuan)質(zhi)速(su)率較低(di),導致在貧氮(dan)(dan)鐵(tie)素體(ti)(ti)相(xiang)(xiang)枝(zhi)(zhi)(zhi)晶附近的(de)(de)(de)(de)(de)(de)(de)液(ye)(ye)相(xiang)(xiang)中出現氮(dan)(dan)富(fu)集(ji),且[%N]iq迅(xun)速(su)增(zeng)大(da),如圖2-55(a)所(suo)示(shi)。根據Yang和(he)(he) Leel70]、Svyazhin 等、Ridolfi 和(he)(he) Tassal的(de)(de)(de)(de)(de)(de)(de)報道可知(zhi),當[%N]iq的(de)(de)(de)(de)(de)(de)(de)最大(da)值超過(guo)氮(dan)(dan)氣(qi)泡形成(cheng)的(de)(de)(de)(de)(de)(de)(de)臨界氮(dan)(dan)質(zhi)量(liang)分數([%N]pore)時,該區(qu)(qu)域(yu)有氣(qi)泡形成(cheng)的(de)(de)(de)(de)(de)(de)(de)可能性,如圖2-55(b)所(suo)示(shi)。在后續的(de)(de)(de)(de)(de)(de)(de)凝(ning)(ning)固(gu)過(guo)程(cheng)中,隨(sui)著(zhu)(zhu)包晶反應的(de)(de)(de)(de)(de)(de)(de)進(jin)行,富(fu)氮(dan)(dan)奧氏體(ti)(ti)相(xiang)(xiang)γ以(yi)異質(zhi)形核的(de)(de)(de)(de)(de)(de)(de)方(fang)式在鐵(tie)素體(ti)(ti)相(xiang)(xiang)8枝(zhi)(zhi)(zhi)晶的(de)(de)(de)(de)(de)(de)(de)表面(mian)開始形核長大(da),逐(zhu)漸包裹鐵(tie)素體(ti)(ti)相(xiang)(xiang)枝(zhi)(zhi)(zhi)晶表面(mian),并(bing)開始捕(bu)獲殘余液(ye)(ye)相(xiang)(xiang)中的(de)(de)(de)(de)(de)(de)(de)氮(dan)(dan)氣(qi)泡,對比(bi)圖2-51和(he)(he)圖2-56可知(zhi),此時枝(zhi)(zhi)(zhi)晶間(jian)(jian)(jian)殘余[%N]1ig的(de)(de)(de)(de)(de)(de)(de)增(zeng)長速(su)率減(jian)小(xiao)。對平(ping)衡凝(ning)(ning)固(gu)而言(yan),殘余液(ye)(ye)相(xiang)(xiang)中氮(dan)(dan)氣(qi)泡形成(cheng)以(yi)后,氮(dan)(dan)的(de)(de)(de)(de)(de)(de)(de)富(fu)集(ji)程(cheng)度(du)減(jian)弱,[%N]1iq增(zeng)長速(su)率的(de)(de)(de)(de)(de)(de)(de)減(jian)小(xiao)程(cheng)度(du)明顯;相(xiang)(xiang)比(bi)之下,Scheil凝(ning)(ning)固(gu)過(guo)程(cheng)中,氮(dan)(dan)氣(qi)泡形成(cheng)以(yi)后,殘余液(ye)(ye)相(xiang)(xiang)中氮(dan)(dan)富(fu)集(ji)狀(zhuang)態(tai)有所(suo)緩解(jie),但(dan)幅度(du)很小(xiao)。隨(sui)著(zhu)(zhu)凝(ning)(ning)固(gu)界面(mian)的(de)(de)(de)(de)(de)(de)(de)進(jin)一步(bu)推移,被捕(bu)獲的(de)(de)(de)(de)(de)(de)(de)氮(dan)(dan)氣(qi)泡在奧氏體(ti)(ti)相(xiang)(xiang)表面(mian)開始長大(da),并(bing)沿(yan)凝(ning)(ning)固(gu)方(fang)向拉(la)長,如圖2-55(c)所(suo)示(shi)。



  氮(dan)氣孔(kong)沿徑向生長(chang),生長(chang)方向與凝固(gu)(gu)方向一致,那么氮(dan)氣孔(kong)初始形(xing)成(cheng)(cheng)位(wei)(wei)置(zhi)靠近鑄(zhu)錠邊部,且(qie)氮(dan)氣泡(pao)初始位(wei)(wei)置(zhi)邊緣全(quan)由奧氏體(ti)相(xiang)(xiang)(xiang)γ構(gou)成(cheng)(cheng)(圖2-57中I區),與圖2-55描述相(xiang)(xiang)(xiang)符。隨(sui)著氮(dan)氣孔(kong)被(bei)拉長(chang),鐵素體(ti)相(xiang)(xiang)(xiang)和奧氏體(ti)相(xiang)(xiang)(xiang)以(yi)體(ti)積(ji)分數比約為(wei)0.92的(de)關(guan)系交替在(zai)氮(dan)氣泡(pao)周圍形(xing)成(cheng)(cheng),直到氮(dan)氣孔(kong)閉合。凝固(gu)(gu)結(jie)束后(hou),氮(dan)氣孔(kong)的(de)宏觀形(xing)貌類似于橢圓形(xing),與Wei等的(de)研究結(jie)果一致



二(er)、氮(dan)微(wei)觀偏析對(dui)氮(dan)氣孔(kong)的影響


  氮(dan)(dan)(dan)(dan)的(de)(de)(de)分(fen)配系(xi)數(shu)較小,導致液(ye)相(xiang)向(xiang)固(gu)(gu)相(xiang)轉變(bian)的(de)(de)(de)過(guo)程(cheng)中(zhong)(zhong),固(gu)(gu)相(xiang)會將多余(yu)(yu)的(de)(de)(de)氮(dan)(dan)(dan)(dan)轉移到殘(can)余(yu)(yu)液(ye)相(xiang)中(zhong)(zhong),形(xing)成(cheng)(cheng)(cheng)(cheng)氮(dan)(dan)(dan)(dan)偏析(xi)。在氮(dan)(dan)(dan)(dan)偏析(xi)程(cheng)度(du)逐漸加(jia)重(zhong)的(de)(de)(de)過(guo)程(cheng)中(zhong)(zhong),當殘(can)余(yu)(yu)液(ye)相(xiang)中(zhong)(zhong)氮(dan)(dan)(dan)(dan)質量分(fen)數(shu)超(chao)過(guo)其飽和(he)度(du)時(shi),極易(yi)形(xing)成(cheng)(cheng)(cheng)(cheng)氮(dan)(dan)(dan)(dan)氣(qi)泡。隨著凝(ning)(ning)固(gu)(gu)的(de)(de)(de)進行,若(ruo)氣(qi)泡無法上浮而被捕獲,凝(ning)(ning)固(gu)(gu)結束后就(jiu)會在鑄錠內(nei)部形(xing)成(cheng)(cheng)(cheng)(cheng)氣(qi)孔(kong)(kong)。因(yin)(yin)此(ci),凝(ning)(ning)固(gu)(gu)過(guo)程(cheng)中(zhong)(zhong)氮(dan)(dan)(dan)(dan)偏析(xi)和(he)溶解度(du)對(dui)鑄錠中(zhong)(zhong)最(zui)終氮(dan)(dan)(dan)(dan)氣(qi)孔(kong)(kong)的(de)(de)(de)形(xing)成(cheng)(cheng)(cheng)(cheng)有至關重(zhong)要(yao)的(de)(de)(de)作用(yong)。氮(dan)(dan)(dan)(dan)氣(qi)孔(kong)(kong)多數(shu)情況下與疏(shu)松(song)縮(suo)(suo)(suo)孔(kong)(kong)共存(cun),內(nei)壁凹凸不(bu)平(ping)呈現(xian)裂紋狀,且整個(ge)氣(qi)孔(kong)(kong)形(xing)狀不(bu)規則,如圖2-58所示(shi)。此(ci)類(lei)氣(qi)孔(kong)(kong)不(bu)僅與鋼(gang)液(ye)中(zhong)(zhong)氣(qi)泡的(de)(de)(de)形(xing)成(cheng)(cheng)(cheng)(cheng)有關,還受凝(ning)(ning)固(gu)(gu)收(shou)縮(suo)(suo)(suo)等因(yin)(yin)素的(de)(de)(de)影響(xiang),且多數(shu)分(fen)布于鑄錠心部,尤其在中(zhong)(zhong)心等軸(zhou)晶(jing)區(qu)。這主要(yao)由于中(zhong)(zhong)心等軸(zhou)晶(jing)區(qu)內(nei)枝晶(jing)生(sheng)(sheng)長較發(fa)達,容易(yi)形(xing)成(cheng)(cheng)(cheng)(cheng)復雜(za)的(de)(de)(de)網狀結構,從(cong)而將液(ye)相(xiang)分(fen)割成(cheng)(cheng)(cheng)(cheng)無數(shu)個(ge)獨立的(de)(de)(de)液(ye)相(xiang)區(qu)域(yu),當發(fa)生(sheng)(sheng)凝(ning)(ning)固(gu)(gu)收(shou)縮(suo)(suo)(suo)時(shi),難(nan)以進行補縮(suo)(suo)(suo),在形(xing)成(cheng)(cheng)(cheng)(cheng)疏(shu)松(song)縮(suo)(suo)(suo)孔(kong)(kong)的(de)(de)(de)同(tong)時(shi),局部鋼(gang)液(ye)靜(jing)壓力降低,促使(shi)氮(dan)(dan)(dan)(dan)從(cong)殘(can)余(yu)(yu)液(ye)相(xiang)中(zhong)(zhong)析(xi)出,從(cong)而形(xing)成(cheng)(cheng)(cheng)(cheng)了氮(dan)(dan)(dan)(dan)氣(qi)孔(kong)(kong)和(he)疏(shu)松(song)縮(suo)(suo)(suo)孔(kong)(kong)共存(cun)的(de)(de)(de)宏(hong)觀缺陷(xian)。


圖 58.jpg



  平(ping)衡(heng)凝(ning)固時(shi),19Cr14Mn0.9N含(han)氮(dan)(dan)奧(ao)氏體不銹鋼殘余液相中(zhong)氮(dan)(dan)偏析與體系氮(dan)(dan)溶解度的(de)(de)差(cha)值(zhi)如圖(tu)2-59所示。凝(ning)固初期鐵素(su)體阱(ferrite trap)的(de)(de)形成,導致氮(dan)(dan)溶解度的(de)(de)降低,進而使氮(dan)(dan)偏析與體系氮(dan)(dan)溶解度差(cha)值(zhi)呈現出略微增大的(de)(de)趨勢(shi)。但在(zai)后續凝(ning)固過(guo)程(cheng)中(zhong),隨(sui)著鐵素(su)體阱的(de)(de)消(xiao)失以及(ji)富氮(dan)(dan)奧(ao)氏體相的(de)(de)不斷形成,差(cha)值(zhi)減(jian)小(xiao);在(zai)整(zheng)個凝(ning)固過(guo)程(cheng)中(zhong)差(cha)值(zhi)始終較小(xiao),且變化幅度較窄。對于19Cr14Mn0.9N 含(han)氮(dan)(dan)奧(ao)氏體不銹鋼,液相中(zhong)氮(dan)(dan)氣泡的(de)(de)形成趨勢(shi)較小(xiao),難(nan)以在(zai)鑄錠內形成獨(du)立內壁光滑的(de)(de)規則氮(dan)(dan)氣孔。


  此(ci)外,目前有人(ren)對奧(ao)氏(shi)體鋼(gang)(gang)(gang)凝(ning)固(gu)過(guo)程(cheng)(cheng)中(zhong)(zhong)(zhong)(zhong)(zhong)氮(dan)(dan)氣(qi)(qi)(qi)(qi)孔的形(xing)成(cheng)進行(xing)了(le)大(da)(da)量研(yan)究(jiu),如Yang和Leel901研(yan)究(jiu)了(le)奧(ao)氏(shi)體鋼(gang)(gang)(gang)16Cr3NixMn(x=9和11)凝(ning)固(gu)過(guo)程(cheng)(cheng)中(zhong)(zhong)(zhong)(zhong)(zhong)壓(ya)力和初始(shi)(shi)氮(dan)(dan)質量分(fen)數等因素(su)對氮(dan)(dan)氣(qi)(qi)(qi)(qi)孔形(xing)成(cheng)的影響規(gui)律(lv),并(bing)建立了(le)相(xiang)應的預測模型。Ridolfi和Tassal[84]分(fen)析了(le)氮(dan)(dan)偏析、合(he)金元素(su)、冷(leng)卻(que)速(su)率以(yi)(yi)及枝晶間距對奧(ao)氏(shi)體鋼(gang)(gang)(gang)中(zhong)(zhong)(zhong)(zhong)(zhong)氮(dan)(dan)氣(qi)(qi)(qi)(qi)孔的影響規(gui)律(lv),并(bing)揭示了(le)奧(ao)氏(shi)體鋼(gang)(gang)(gang)中(zhong)(zhong)(zhong)(zhong)(zhong)氮(dan)(dan)氣(qi)(qi)(qi)(qi)孔形(xing)成(cheng)機理。然而(er),目前對于(yu)雙相(xiang)鋼(gang)(gang)(gang)中(zhong)(zhong)(zhong)(zhong)(zhong)氮(dan)(dan)氣(qi)(qi)(qi)(qi)孔形(xing)成(cheng)的研(yan)究(jiu)較(jiao)少,且主(zhu)要集中(zhong)(zhong)(zhong)(zhong)(zhong)在(zai)合(he)金元素(su)、鑄造方式、冷(leng)卻(que)速(su)率等因素(su)對氮(dan)(dan)氣(qi)(qi)(qi)(qi)孔影響規(gui)律(lv)的研(yan)究(jiu),鮮有對雙相(xiang)鋼(gang)(gang)(gang)中(zhong)(zhong)(zhong)(zhong)(zhong)氮(dan)(dan)氣(qi)(qi)(qi)(qi)孔形(xing)成(cheng)機理的報道。以(yi)(yi)21.5Cr5Mn1.5Ni0.25N含氮(dan)(dan)雙相(xiang)鋼(gang)(gang)(gang)為例,氮(dan)(dan)偏析與溶解度(du)的差值(zhi)在(zai)整(zheng)個凝(ning)固(gu)過(guo)程(cheng)(cheng)中(zhong)(zhong)(zhong)(zhong)(zhong)的變化趨(qu)勢,如圖2-59所(suo)示。隨著凝(ning)固(gu)的進行(xing),氮(dan)(dan)偏析始(shi)(shi)終大(da)(da)于(yu)氮(dan)(dan)溶解度(du),且差值(zhi)呈現出(chu)快速(su)增(zeng)大(da)(da)的趨(qu)勢。因此(ci),在(zai)21.5Cr5Mn1.5Ni0.25N 含氮(dan)(dan)雙相(xiang)鋼(gang)(gang)(gang)凝(ning)固(gu)過(guo)程(cheng)(cheng)中(zhong)(zhong)(zhong)(zhong)(zhong),氮(dan)(dan)偏析嚴重,殘余液相(xiang)內氮(dan)(dan)氣(qi)(qi)(qi)(qi)泡(pao)形(xing)成(cheng)趨(qu)勢較(jiao)大(da)(da),明顯高于(yu)19Cr14Mn0.9N含氮(dan)(dan)奧(ao)氏(shi)體不銹(xiu)鋼(gang)(gang)(gang)。


圖 59.jpg

  氮(dan)氣(qi)泡(pao)形成和長大(da)(da)具有(you)重要的(de)(de)作(zuo)用(yong)(圖2-60).其中,σ為氣(qi)液界面(mian)的(de)(de)表面(mian)張力(li)(li),r為氣(qi)泡(pao)半徑。結合經典形核理(li)論,氮(dan)氣(qi)泡(pao)在鋼液中穩定存在的(de)(de)必要條件為氣(qi)泡(pao)內壓力(li)(li)大(da)(da)于作(zuo)用(yong)于氣(qi)泡(pao)的(de)(de)所有(you)壓力(li)(li)之和,即


圖 60.jpg


  式中(zhong),Aso由凝(ning)固過程中(zhong)除氮(dan)以外其(qi)他(ta)合(he)(he)金元素的(de)(de)微觀(guan)偏析(xi)進行計(ji)(ji)算,其(qi)值隨(sui)著枝(zhi)(zhi)(zhi)晶(jing)間殘余(yu)液(ye)相(xiang)(xiang)中(zhong)氮(dan)溶(rong)解度的(de)(de)增(zeng)加而減小,表征(zheng)(zheng)了枝(zhi)(zhi)(zhi)晶(jing)間殘余(yu)液(ye)相(xiang)(xiang)中(zhong)氮(dan)溶(rong)解度對氮(dan)氣(qi)泡形成的(de)(de)影響程度;Ase表征(zheng)(zheng)了枝(zhi)(zhi)(zhi)晶(jing)間氮(dan)偏析(xi)對氮(dan)氣(qi)泡形成的(de)(de)影響程度,可由凝(ning)固過程中(zhong)枝(zhi)(zhi)(zhi)晶(jing)間殘余(yu)液(ye)相(xiang)(xiang)中(zhong)氮(dan)偏析(xi)計(ji)(ji)算獲得,其(qi)值隨(sui)著氮(dan)偏析(xi)的(de)(de)增(zeng)大而增(zeng)大。此外,用于(yu)計(ji)(ji)算Aso和Ase時(shi)所需的(de)(de)合(he)(he)金元素偏析(xi)均由鋼凝(ning)固相(xiang)(xiang)變所致。


  氮(dan)氣(qi)泡(pao)的形(xing)(xing)核(he)和(he)長大(da)過(guo)(guo)程(cheng)(cheng)復雜,且影響(xiang)因(yin)素眾(zhong)多,包括凝(ning)(ning)固(gu)(gu)收縮、冶煉環(huan)境(jing)以(yi)及(ji)坩堝材質等(deng)(deng)。因(yin)此(ci)(ci),很(hen)難采用(yong)Pg值精(jing)確預測(ce)凝(ning)(ning)固(gu)(gu)過(guo)(guo)程(cheng)(cheng)中(zhong)氮(dan)氣(qi)泡(pao)的形(xing)(xing)成(cheng)和(he)長大(da)。然而基(ji)于Yang等(deng)(deng)的實(shi)(shi)驗研究[70,77],在評估凝(ning)(ning)固(gu)(gu)壓(ya)力、合金成(cheng)分(fen)(fen)等(deng)(deng)因(yin)素對氮(dan)氣(qi)泡(pao)形(xing)(xing)成(cheng)的影響(xiang)程(cheng)(cheng)度(du)時,Pg起關鍵作用(yong)。實(shi)(shi)際(ji)凝(ning)(ning)固(gu)(gu)過(guo)(guo)程(cheng)(cheng)介于平衡凝(ning)(ning)固(gu)(gu)(固(gu)(gu)/液相中(zhong)溶質完(wan)全擴散(san))和(he)Scheil凝(ning)(ning)固(gu)(gu)(固(gu)(gu)相無(wu)溶質擴散(san),液相中(zhong)完(wan)全擴散(san))之間70].因(yin)此(ci)(ci),可分(fen)(fen)別計算平衡凝(ning)(ning)固(gu)(gu)和(he)Scheil凝(ning)(ning)固(gu)(gu)過(guo)(guo)程(cheng)(cheng)中(zhong)的Aso、Ase和(he)Pg,闡(chan)明(ming)實(shi)(shi)際(ji)凝(ning)(ning)固(gu)(gu)過(guo)(guo)程(cheng)(cheng)中(zhong)壓(ya)力等(deng)(deng)因(yin)素對氮(dan)氣(qi)泡(pao)形(xing)(xing)成(cheng)的影響(xiang)規律。


  現以21.5Cr5Mn1.5Ni0.25N含氮雙相(xiang)鋼D1鑄(zhu)錠為例,對凝固(gu)過程(cheng)中(zhong)Aso、Ase和P8的(de)變(bian)(bian)化(hua)趨勢(shi)進行計算。圖2-61描述了(le)ΔAso(=Asa-Aso,0)和AAse(=Ase-Ase,o)隨固(gu)相(xiang)質量分(fen)數的(de)變(bian)(bian)化(hua)趨勢(shi)(Aso,0和Asc,0分(fen)別為D1鑄(zhu)錠凝固(gu)時Aso和Ase的(de)初始值(zhi))。


  在(zai)(zai)平衡(heng)凝(ning)(ning)(ning)固(gu)(gu)和(he)(he)Scheil凝(ning)(ning)(ning)固(gu)(gu)過(guo)程(cheng)中,ΔAso的(de)(de)(de)最小值分(fen)(fen)別(bie)(bie)為-0.145和(he)(he)-0.397,與(yu)(yu)此(ci)(ci)相(xiang)對(dui)應的(de)(de)(de)ΔAse值最大(da)(da)(da),分(fen)(fen)別(bie)(bie)為0.68和(he)(he)0.92.在(zai)(zai)整個凝(ning)(ning)(ning)固(gu)(gu)過(guo)程(cheng)中,由于(yu)ΔAse與(yu)(yu)ΔAso之(zhi)和(he)(he)始(shi)終大(da)(da)(da)于(yu)零,因而枝晶間(jian)殘余液相(xiang)中氮(dan)(dan)(dan)偏析對(dui)D1 鑄(zhu)錠凝(ning)(ning)(ning)固(gu)(gu)過(guo)程(cheng)中氮(dan)(dan)(dan)氣泡形(xing)成的(de)(de)(de)影(ying)響大(da)(da)(da)于(yu)氮(dan)(dan)(dan)溶解度,起主導作用。此(ci)(ci)外(wai),在(zai)(zai)整個凝(ning)(ning)(ning)固(gu)(gu)過(guo)程(cheng)中,P8變(bian)化趨(qu)勢如圖2-62所示(shi),其變(bian)化規律(lv)(lv)與(yu)(yu)Young等。的(de)(de)(de)研(yan)究結果一致,Pg的(de)(de)(de)最大(da)(da)(da)值Pg與(yu)(yu)Ase+Aso的(de)(de)(de)最大(da)(da)(da)值相(xiang)對(dui)應,且在(zai)(zai)平衡(heng)凝(ning)(ning)(ning)固(gu)(gu)和(he)(he) Scheil 凝(ning)(ning)(ning)固(gu)(gu)過(guo)程(cheng)中分(fen)(fen)別(bie)(bie)為0.63MPa和(he)(he)0.62MPa.此(ci)(ci)外(wai),可通過(guo)對(dui)比不同鑄(zhu)錠中的(de)(de)(de)探討凝(ning)(ning)(ning)固(gu)(gu)壓力、初始(shi)氮(dan)(dan)(dan)質量分(fen)(fen)數以及合金(jin)元素(su)(鉻和(he)(he)錳)等對(dui)液相(xiang)中氮(dan)(dan)(dan)氣泡形(xing)成的(de)(de)(de)影(ying)響,進(jin)而明晰各因素(su)對(dui)氮(dan)(dan)(dan)氣孔形(xing)成的(de)(de)(de)影(ying)響規律(lv)(lv)。


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